纳米金属薄膜与颗粒制备实验室

人工结构光电功能材料与器件实验室

脉冲激光沉积实验室

化学法沉积制备实验室

实验室介绍 6

	纳米金属薄膜与颗粒制备实验室是材料科学与工程系最早建立的几个实验室之一，主要研究纳米金属与纳米涂层材料的可控制备及其在微电子互连、微电机系统等现代工程领域中的应用。研究方向包括微电机系统及微电子互连金属薄膜性能的尺度效应，纳米金属颗粒的可控制备及其性能表征，纳米涂层材料的制备及其工程应用，纳米材料若干性能的模拟计算。先后承担国家重大基础研究计划（973计划）、国家自然科学基金，江苏省自然科学基金等10余项研究项目，在国内外重要学术期刊发表SCI论文100余篇，申请、获得国家发明专利10余项，获省部级科技进步奖励4项。

实验室成员 6

4	教授：孟祥康副教授：陆海鸣、唐少春博士后：操振华、李平云、任华博士研究生：陆洪彬、汪蕾、陈兰、胡坤、苏英杰、Syed Junaid Ali、Arsalan Ahmed 硕士研究生：郑洲、周友珍、佘茜玮、王阳、韩源源已出站博士后：陆海鸣、Vongehr Sascha 已毕业研究生：胥伟华、王凯良、孟大润、华文宇、何伟业、黄建国、丁道宁、唐少春、徐春、朱少鹏、刘澎、操振华、李平云

Recent Publications 6

(*Corresponding author)
[1] Tang SC, Vongehr S and Meng XK*, Controllable incorporation of Ag and Ag-Au nanoparticles in carbon spheres for tunable optical and catalytic properties, J. Mater. Chem. 20 (2010)5436-5445.
[2] Lu HM and Meng XK*, Theoretical model to calculate catalytic activation energies of platinum nanoparticles of different sizes and shapes, J. Phys. Chem. C, 114 (2010)1534-1538.
[3] Tang SC, Vongehr S and Meng XK*, Carbon spheres with controllable silver nanoparticle doping, J. Phys. Chem. C, 114 (2010)977-982.
[4] Lu HM and Meng XK*, Size Dependence of Magnetostructural Transition in MnBi Nanorods, J. Phys. Chem. C, 114 (2010) 2932-2935.
[5] Huang JF, Vongehr S, Tang SC, Lu HM and Meng XK*, Highly catalytic Pd-Ag bimetallic dendrites, J. Phys. Chem. C, 114(2010) 15005-15010.
[6] Tang SC, Vongehr S, Zhou Z, Liu HJ and Meng XK*, Silver doping mediated route to bimetallically doped carbon spheres with controllable nanoparticle distributions, J. Phys. Chem. C, 114 (2010)15863-15871.
[7] Lu HM and Meng XK*, Morin Temperature and Néel Temperature of Hematite Nanocrystals, J. Phys. Chem. C, 114 (2010) 21291-21295.
[8] Cao ZH, Wang F, Wang L and Meng XK*, Coupling effect of electric and thermal fields on growth of nanocrystalline copper films, Phys. Rev. B, 81(2010) 113405.
[9] Tang SC, Lan Chen, Vongehr S and Meng XK*, Co dendrite based bimetallic structures with nanoflake-built Pt covers and strong catalytic activity, J. Colloid Interf. Sci., 351(2010)217-224.
[10] Cao ZH, Huang YL and Meng XK*, Size dependent rate sensitivity and plasticity of nanocrystalline Ru films, Scripta Mater., 63(2010)993-996.
[11] Tang SC, Lan Chen, Vongehr S, Wang Y and Meng XK*, Ethanol-assisted hydrothermal synthesis and electrochemical properties of coral-like β-Co(OH)2 nanostructures, J. Solid State Chem., 183(2010) 2166-2173.
[12] Lu HB, Hu Y, Gu MH, Tang SC, Lu HM and Meng XK*, Corr. Synthesis and characterization of silica-acrylic- epoxy hybrid coatings on 430 stainless steel, Surf. Coat. Tech., 204(2010)1658.
[13] Xu F, Xu YD, Meng XK*, Chen YF, Lu HM, Zhang Y, Zhang LT, Cheng LF and Fan SW, Int. J. Appl. Ceram. Tech., 7(2010)268-276.
[14] Tang SC, Lan Chen, Vongehr S and Meng XK*, Heterogeneous nucleation and growth of silver nanoparticles on unmodified polystyrene spheres by in situ reduction, Appl. Surf. Sci. 256 (2010)2654-2660.
[15] Lu HM and Meng XK, Size-Dependent Nonmagnetic Surface Layer of Ferromagnetic Nanoparticles, J. Nanosci. Nanotechno., 10(2010)7498–7500.
[16] Vongehr S. Tang SC and Meng XK*, Collision statistics of clusters: from Poisson model to Poisson mixtures, Chin. Phys. B, 19(2010)023602.
[17] Meng XK*, Tang SC and Vongehr S, A Review on Diverse Silver Nanostructures (Invited Review), J. Mater. Sci. Tech., 26(2010)487-522.
[18] Tang SC, Meng XK* and Vongehr S, Synthesis of large-area copper nano- octahedra on gold film substrates, Electrochem. Commun., 11(2009)867- 870.
[19] Lu HM, Li PY, Cao ZH and Meng XK*, Size, shape, and dimensionality dependent melting temperatures of nanocrystals, J. Phys. Chem. C, 113(2009) 7598-7602.
[20] Huang JF, Vongehr S, Tang SC, Lu HM, Shen JC and Meng XK*, Ag dendrite-based Au/Ag bimetallic nanostructures with strongly enhanced catalytic activity, Langmuir, 25(2009)11890-11896.
[21] Li PY, Lu HM, Cao ZH, Tang SC, Meng XK*, Li XS and Jiang ZH, Order-disorder transition and Curie transition in Ni70Fe30 nanoalloy, Appl. Phys. Lett., 94(2009)213112.
[22] Tang SC, Vongehr S and Meng XK*, Two distinct branch–stem interfacial structures of silver dendrites with vertical and slanted branchings, Chem. Phys. Lett., 477(2009)179-183.
[23] Li PY, Lu HM, Tang SC and Meng XK*, An in-situ TEM investigation on microstructure evolution of Ni-25 at.% Al thin films, J. Alloys Compd., 478(2009)240-245.
[24] Cao ZH, Li PY, Lu HM, Huang YL and Meng XK*, Thickness and grain size dependent mechanical properties of Cu films studied by nanoindentation tests, J. Phys. D: Appl. Phys., 42(2009)065405.
[25] Xu C, Xia YD, Liu ZG and Meng XK*, Chemical states change at (Ba,Sr)TiO3/Pt interfaces investigated by x-ray photoelectron spectroscopy, J. Phys. D: Appl. Phys., 42(2009)085302.
[26] Lu HM, Li PY, Huang YN and Meng XK*, Zhang XY and Liu Q, Size dependent Curie transition of Ni nanocrystals, J. Appl. Phys., 105(2009)023516.
[27] Cao ZH, Lu HM, Meng XK* and Ngan AHW, Indentation size dependent plastic deformation of nano crystalline and ultrafine grain Cu films at nanoscale, J. Appl. Phys., 105(2009)083521.
[28] Cao ZH, Hu K and Meng XK*, Diffusion barrier properties of amorphous and nanocrystalline Ta films for Cu interconnects, J. Appl. Phys., 106(2009)113513.
[29] Cao ZH, Li PY, Lu HM, Huang YL, Zhou YC and Meng XK*, Indentation size effects on the creep behavior of nanocrystalline tetragonal Ta films, Scripta Mater., 60(2009)415-418.
[30] Tang SC, Meng XK*, Lu HB and Zhu SP, PVP-assisted sonoelectrochemical growth of silver nanostructures with various shapes, Mater. Chem. Phys., 116(2009)464-468.
[31] Cao ZH, Lu HM and Meng XK*, Barrier layer and annealing temperature dependent microstructure evolution of nanocrystalline Cu films, Mater. Chem. Phys., 117(2009)321-325.
[32] Zhu SP, Huang JF, Tang SC and Meng XK*, Synthesis of Ag microparticles with hierarchical nanostructure on the anode of a galvanic cell, Mater. Chem. Phys., 118(2009)442-446.
[33] Tang SC, Meng XK*, Wang CC and Cao ZH, Flowerlike Ag microparticles with novel nanostructure synthesized by an electrochemical approach, Mater. Chem. Phys., 114(2009)842-847.
[34] Tang SC, Tang YF, Vongehr S, Zhao XN and Meng XK*, Nanoporous carbon spheres and their application in dispersing silver nanoparticles, Appl. Surf. Sci., 255(2009)6011-6016.
[35] Cao ZH, Liu P, Meng XK*, Tang SC and Lu HM, In situ transmission electron microscopy observations of the crystallization of amorphous Ge films, Appl. Phys. A, 94(2009)393-398.
[36] Li PY, Cao ZH, Zhang XY, Wu XL, Huang YN and Meng XK*, Curie transition of NC nickel by mechanical spectroscopy and magnetization study, Chin. Phys. Lett., 26(2009)036102.
[37] Zhu SP, Tang SC and Meng XK*, Monodisperse silver nanoparticles synthesized by a microwave-assisted method, Chin. Phys. Lett., 26(2009)078101.
[38] Cao ZH, Li PY and Meng XK*,Nanoindentation creep behaviors of amorphous, tetragonal, and bcc Ta films, Mater. Sci. Eng., A, 516(2009)253-258.
[39] Lu HB, Hu Y, Gu MH, Tang SC, Lu HM and Meng XK*, Synthesis and characterization of silica-acrylic- epoxy hybrid coatings on 430 stainless steel, Surf. Coat. Tech., 204(2009)91-98.
[40] Lu HB, Gu MH, Huang JF, Hu Y and Meng XK*, In-situ polymerized nanosilica/acrylic/epoxy hybrid coating: Preparation, microstructure and properties, Sci. China, Ser. E, 52(2009)2204-2209.
[41] Tang SC and Meng XK*, Controllable synthesis of metal particles by a direct current electrochemical approach, Sci. China, Ser. E, 52(2009)2709-2714.
[42] Wang XS, Li Y and Meng XK, Estimating method on the failure stress of micro thickness Cu film-substrate structure, Sci. China, Ser. E, 52(2009) 2210-2215.
[43] Gao F, Lu QY, Meng XK and Komarneni S, CdS nanorod-based structures: From two- and three- dimensional leaves to flowers, J. Phys. Chem. C, 112 (2008) 13359- 13365.
[44] Xia YD, Yin KB, Xu C, Zhang Y, Xu B, He WY, Meng XK*, Yin J and Liu ZG, Studies of two distinct types of (Ba,Sr)TiO3/Pt interfaces, Appl. Phys. Lett., 92(2008)102906.
[45] Li Y, Wang XS and Meng XK, Buckling behavior of metal film/substrate structure under pure bending, Appl. Phys. Lett., 92(2008)131902.
[46] Lu HM, Han FQ and Meng XK*, Size-dependent thermodynamic properties of metallic nanowires, J. Phys. Chem. B, 112 (2008) 9444-9448.
[47] Tang SC, Zhu SP, Lu HM and Meng XK*, Shape evolution and thermal stability of Ag nanoparticle on spherical SiO2 substrates, J. Solid State Chem., 181 (2008) 587-592.
[48] Lu HM, Cao ZH, Zhao CL, Li PY and Meng XK*, Size-dependent ordering and Curie temperatures of FePt nanoparticles, J. Appl. Phys., 103(2008)123526.
[49] Gao F, Lu QY., Meng XK and Komarneni S, Synthesis of nanorods and nanowires using biomolecules under conventional- and microwave-hydrothermal conditions, J. Mater. Sci., 43(2008)2377-2386.
[50] Li PY, Zhang XY, Wu XL, Huang YN, Meng XK*, Internal Friction of Bend-Deformed Nanocrystalline Nickel by Mechanical Spectroscopy, Chin. Phys. Lett., 25(2008) 4339-4341.
[51] Wang XS, Yan CK, Li Y, Xue YB, Meng XK and Wu BS, SEM in-situ investigation on failure of nanometallic film/substrate structures under three-point bending loading, Int. J. Fract., 151 (2008) 269-279.
[52] Xu F, Zhang LT, Meng XK, Chen YF, Xu YD, Fan SW and Zhang Y, Microstructure of C/SiC braking material, J. Inorg. Mater., 23(2008)233-237.
[53] Lu HM, Ding DN, Cao ZH, Tang SC and Meng XK*, Surface energy and melting temperature of elemental nanocavities, J. Phys. Chem. C, 111 (2007) 12914- 12917.
[54] Lu HM, Zhao CL, Tang SC and Meng XK*, Does the nonmagnetic surface layer exist throughout ferromagnetic nanoparticles, J. Phys. Chem. C, 111(2007)18585- 18588.
[55] Xia YD, He WY, Chen L, Meng XK and Liu ZG, Field induced resistive switching based on space charge limited current, Appl. Phys. Lett., 90 (2007) 022907.
[56] Xia YD, Liu ZG, Wang Y, Shi L, Chen L, Yin J and X.K.Meng, Conduction behavior change responsible for the resistive switching as investigated by complex impedance spectroscopy, Appl. Phys. Lett., 91 (2007) 102904.
[57] Tang SC, Tang YF, Gao F, Liu ZG and Meng XK*, Ultrasonic electrodeposition of silver nanoparticles on dielectric silica spheres, Nanotechnology, 18 (2007) 295607.
[58] Tang SC, Tang YF, Zhu SP, Lu HM and Meng XK*, Synthesis and characterization of silica-silver core-shell composite particle swith uniform thin silver layers, J. Solid State Chem., 180 (2007) 2871-2876.
[59] Huang JG, Wang XS and Meng XK*, SEM in situ study on deformation behavior of Cu and Cu/Ni films under three-point bending, Mater. Trans., 48 (2007) 2795-2798.

获奖情况 6

[1] 金属表面高性能纳米防护涂层技术及其产业化，教育部科技进步二等奖，2010（排名第一）
[2] 贝氏体在Cu基合金中的形成过程，教育部科技进步三等奖，1995（排名第二）
[3] 原子探针场离子显微术在材料微结构研究的应用，教育部科技进步二等奖，1995（排名第三）
[4] 合金中的贝氏体预相变，陕西省科技进步二等奖，1997（排名第四）

科研项目 6

[1] 材料介观性能尺度效应的结构特征，973计划，2004CB619305
[2] 材料介观特性及其多场服役失效行为的微结构特征，973计划，2010CB631004
[3] 一类新型复合膜的制备与性能研究，国家自然科学基金，59981003
[4] 晶核－晶壳纳米颗粒的界面结构与性能研究，国家自然科学基金，50571044
[5] 粒子改性填缝剂的研制，国家科技人员服务企业行动项目，2009GJC10032
[6] 金属材料尺度效应的微结构表征，江苏省自然科学基金重点项目，BK2006716
[7] 金属防护高性能纳米涂层研究，江苏省产学研联合创新资金项目，BY2009148
[8] 纳米结晶微孔离子过滤膜关键技术研究及产业化，江苏省科技支撑计划项目，BE2009139
[9] 微米金属单晶变形行为及晶体学与尺度效应，国家自然科学基金重点项目，50831004
[10] 纳米颗粒改性动力锂离子电池隔膜关键技术及其产业化，江苏省科技支撑计划（重点）项目

发明专利 6

[1]孟祥康，颜庆云，王凯良，孟大润，华文宇，陈延峰，过冷原子团族控制晶化的纳米合金合成方法。授权号：ZL200310112719.6
[2]孟祥康，唐少春，朱少鹏，陈延峰，大面积均匀分布的铜八面体纳米颗粒的制备方法。授权号：ZL200710190291.5
[3]孟祥康，操振华，李平云，刘澎，徐春，陆海鸣，一种基于模拟IC服役条件的多场耦合装置。授权号：ZL200710191015.0
[4]孟祥康，胡勇，洪亮，朱善忠，丁道宁，顾敏豪，涂层不锈钢。授权号：ZL200820039935.0
[5]孟祥康，唐少春，朱少鹏，陆海鸣，李平云，赵晨林，陈延峰，一步合成并组装铜纳米颗粒的方法。授权号：ZL200710191014.6
[6]孟祥康，唐少春，唐月峰，何伟业，黄建国，丁道宁，陈延峰，刘治国，纳米银包覆二氧化硅的金属介电复合颗粒的制备方法。授权号：ZL200610161202.X
[7]孟祥康，唐少春，陈延峰，负载型花状银纳米结构材料的合成方法。授权号：ZL200810124408.4
[8]胡勇，洪亮，孟祥康，朱善忠，丁道宁，顾敏豪，抗污耐老化不锈钢涂料及其制备方法。授权号：ZL200810019314.0
[9]孟祥康，操振华，刘澎，李平云，陆海鸣，徐春，一种不同相结构的纳米晶金属Ta薄膜的制备方法。申请号：200810022471.7，公开号：CN101323946
[10]孟祥康，陆洪彬，胡勇，顾敏豪，唐少春，朱少鹏，陆海鸣，操振华，李平云，一种高性能金属防护纳米涂层的制备方法。申请号：200910024505.0，公开号：CN101486869
[11]孟祥康，黄建峰，陆洪彬，韩发强，顾敏豪，胡坤，陈兰，唐少春，陆海鸣，一种高效催化活性纳米材料及其制备方法。申请号：200910183351.X，公开号：CN101664678
[12]孟祥康，陆洪彬，吴培龙，陈建国，介孔纳米氧化硅颗粒改性锂离子电池隔膜。申请号：200910263126.7，公开号：CN101710614A
[13]唐少春，孟祥康，银纳米粒子填充微孔碳球制备方法。申请号：201010255943.0，公开号：CN 101934376A
[14]唐少春，孟祥康，一种低成本、高活性的树枝状Co-Pt核壳结构双金属催化剂。申请号：201010615581.1
[15]唐少春，孟祥康，内部填充Ag-M (M = Au、Pd、Pt)双金属粒子的复合碳球的制备方法。申请号：201010614895.X